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Raymond Addleman

Materials & Analytical Chem
Pacific Northwest National Laboratory
PO Box 999
Richland, WA 99352
(509) 375-6824

Biography

A significant portion of our present work focuses primarily upon the development of various surface functionalized nanostructured materials for application to sensing and separation challenges in the environmental and security sectors. Analytes of interest depend upon the application and include selective capture of toxic heavy metals, toxic organic compounds, radionuclides, and explosives. We are also exploring the use of supercritical and near critical fluids as a "green" approach for the synthesis, purification and surface modification of nanomaterials and complex hierarchically ordered structures.

Research Interests

  • My interest focus upon application driven development of advanced materials for sensing, separations energy and catalysis

Selected Publications

2009

  • Busche BJ, RJ Wiacek, JD Davidson, V Koonsiripaiboon, W Yantasee, RS Addleman, and GE Fryxell. 2009. "Synthesis of Nanoporous Iminodiacetic Acid Sorbents for Binding Transition Metals." Inorganic Chemistry Communications 12(4):312-315. 
  • Fernandez CA, JG Roberts, EM Hoppes, GE Fryxell, CM Wang, JT Bays, MG Warner, RJ Wiacek, and RS Addleman. 2009. "Effect of the Ligand Shell Composition on the Dispersibility and Transport of Gold Nanocrystals in Near Critical Solvents." Langmuir 25(9):4900-4906.  doi:10.1021/la804058x
  • Fernandez CA, JG Roberts, EM Hoppes, RJ Wiacek, GE Fryxell, JT Bays, MG Warner, CM Wang, JE Hutchinson, and RS Addleman. 2009. "Advancements Toward the Greener Processing of Engineered Nanomaterials -- Effect of Core Size on the Dispersibility and Transport of Gold Nanocrystals in Near-Critical Solvents." Small 5(8):961-969.  doi:10.1002/smll.200801207

2008

  • Fernandez CA, RJ Wiacek, P Nachimuthu, GE Fryxell, AM Pierson, CL Warner, MG Warner, and RS Addleman. 2008. "A Simple Method for the Prevention of Non-Specific Adsorption by Nanocrystals onto Surfaces." Journal of Nanoscience and Nanotechnology 8(11):5781-5786.  doi:10.1166/jnn.2008.320
  • Yantasee W, B Charnhattakorn, GE Fryxell, Y Lin, C Timchalk, and RS Addleman. 2008. "Detection of Cd, Pb, and Cu in non-pretreated natural waters and urine with thiol functionalized mesoporous silica and Nafion composite electrodes." Analytica Chimica Acta (620):55-63.  doi:10.1016/j.aca.2008.05.029
  • Carter TG, W Yantasee, T Sangvanich, GE Fryxell, DW Johnson, and RS Addleman. 2008. "New functional materials for heavy metal sorption: “Supramolecular” attachment of thiols to mesoporous silica substrates ." Chemical Communications 43:5583-5585.  doi:10.1039/b810576f
  • Fernandez CA, EM Hoppes, JG Bekhazi, CM Wang, RJ Wiacek, MG Warner, GE Fryxell, JT Bays, and RS Addleman. 2008. "Tuning and Quantifying the Dispersibility of Gold Nanocrystals in Liquid and Supercritical Solvents ." Journal of Physical Chemistry C 112(36):13947-13957.  doi:10.1021/jp8038237
  • Yantasee W, K Hongsirikarn, CL Warner, D Choi, T Sangvanich, MB Toloczko, MG Warner, GE Fryxell, RS Addleman, and C Timchalk. 2008. "Direct detection of Pb in urine and Cd, Pb, Cu, and Ag in natural waters using electrochemical sensors immobilized with DMSA functionalized magnetic nanoparticles." The Analyst 133(3):348-355.  doi:10.1039/b711199a

2007

  • Yantasee W, CL Warner, T Sangvanich, RS Addleman, TG Carter, RJ Wiacek, GE Fryxell, C Timchalk, and MG Warner. 2007. "Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized Superparamagnetic Nanoparticles." Environmental Science & Technology 41(14):p.5114-5119.  doi:10.1021/es0705238
  • Yantasee W, Y Lin, K Hongsirikarn, GE Fryxell, RS Addleman, and C Timchalk. 2007. "Electrochemical Sensors for the Detection of Lead and Other Toxic Heavy Metals: The Next Generation of Personal Exposure Biomonitors." Environmental Health Perspectives 115(12):1683-1690. 
  • Dutta D, SK Sundaram, JG Teeguarden, BJ Riley, LS Fifield, JM Jacobs, RS Addleman, GA Kaysen, BM Moudgil, and TJ Weber. 2007. "Adsorbed Proteins Influence the Biological Activity and Molecular Targeting of Nanomaterials." Toxicological Sciences 100(1):303-315.  doi:10.1093/toxsci/kfm217
  • Fryxell GE, SV Mattigod, Y Lin, H Wu, SK Fiskum, KE Parker, F Zheng, W Yantasee, TS Zemanian, RS Addleman, J Liu, J Xu, KM Kemner, S Kelly, and X Feng. 2007. "Design and Synthesis of Self-Assembled Monolayers on Mesoporous Supports (SAMMS): The Importance of Ligand Posture in Functional Nanomaterials." Journal of Materials Chemistry 17:2863-2874.  doi:10.1039/b702422c
  • Zheng F, RS Addleman, CL Aardahl, GE Fryxell, DR Brown, and TS Zemanian. 2007. "Amine Functionalized Nanoporous Materials for Carbon Dioxide Capture." Chapter 12 in Environmental Applications of Nanomaterials: Synthesis, Sorbents and Sensors, ed. Glen E. Fryxell and Guozhong Cao, pp. 285-312.  Imperial College Press, London, United Kingdom. 

2006

2005

  • Addleman RS, MJ O'Hara, JW Grate, and OB Egorov. 2005. "Chemically Enhanced Alpha-Energy Spectroscopy in Liquids." Journal of Radioanalytical and Nuclear Chemistry 263(2):291-294. 
  • Addleman RS, MJ O'Hara, TD Marks, JW Grate, and OB Egorov. 2005. "Direct Actinide Assay with Surface Passivated Silicon Diodes." Journal of Radioanalytical and Nuclear Chemistry 263(2):295-300. 
  • Addleman RS, OB Egorov, MJ O'Hara, BJ Busche, TS Zemanian, and GE Fryxell. 2005. "Preconcentration and Assay of Radionuclides with Self Assembled Monolayers on Mesoporous Supports ." Journal of Radioanalytical and Nuclear Chemistry 263(1):59-64. 
  • Egorov OB, RS Addleman, MJ O'Hara, TD Marks, and JW Grate. 2005. "Direct Measurement of Alpha Emitters in Liquids using Passivated Ion Implanted Planar Silicon (PIPS) Diode Detectors." Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment 537(3):600-609. 
  • Williford RE, RS Addleman, XS Li, TS Zemanian, JC Birnbaum, and GE Fryxell. 2005. "Pore Shape Evolution in Mesoporous Silica Thin Films: from Circular to Elliptical to Rectangular ." Journal of Non-crystalline Solids 351(27-29):2217-2223. 
  • Williford RE, XS Li, RS Addleman, GE Fryxell, S Baskaran, JC Birnbaum, CA Coyle, TS Zemanian, CM Wang, and AR Courtney. 2005. "Mechanical Stability of Templated Mesoporous Silica Thin Films." Microporous and Mesoporous Materials 85(3):260-266. 
  • Zheng F, DN Tran, BJ Busche, GE Fryxell, RS Addleman, TS Zemanian, and CL Aardahl. 2005. "Ethylenediamine-modified SBA-15 as Regenerable CO2 Sorbent." Industrial and Engineering Chemistry Research 44(9):3099-3105.  doi:10.1021/ie049488t

2004

  • Fifield LS, LR Dalton, RS Addleman, RA Galhotra, MH Engelhard, GE Fryxell, and CL Aardahl. 2004. "Noncovalent Functionalization of Carbon Nanotubes with Molecular Anchors using Supercritical Fluids ." Journal of Physical Chemistry B 108(25):8737-8741. 
  • Bitterwolf TE, JD Newell, CT Carver, RS Addleman, JC Linehan, and GE Fryxell. 2004. "Rhodium catalysts bound to functionalized mesoporous silica." Inorganica Chimica Acta 357(10):3001-3006. 
  • Fryxell GE, RS Addleman, SV Mattigod, Y Lin, TS Zemanian, H Wu, JC Birnbaum, J Liu, and X Feng. 2004. "Environmental and Sensing Applications of Molecular Self-Assembly ." In Dekker Encyclopedia of Nanoscience and Nanotechnology, ed. J. A. Schwarz, C. Contescu, K. Putyera, pp. 1135-1145.  Marcel Dekker, New York. 

2003

  • Egorov OB, MJ O'Hara, RS Addleman, and JW Grate. 2003. "Automation of Radiochemical Analysis: From Groundwater Monitoring to Nuclear Waste Analysis." In ACS Symposium Series: Radioanalytical Methods in Interdisciplinary Research. , vol. 868, ed. Carola A. Laue and Kenneth L. Nash, pp. 246-270.  American Chemical Society, Washington D.C.. 

2001

  • Bitterwolf TE, DL Klein, JC Linehan, CR Yonker, and RS Addleman. 2001. "Photochemical Carbonylation of Ethane Under Supercritical Conditions." Angewandte Chemie International Edition 40(14):2692-2694. 
  • Linehan JC, CR Yonker, RS Addleman, T Autrey, JT Bays, TE Bitterwolf, and JL Daschbach. 2001. "Solvent Study of the Kinetics of Molybdenum Radical Self-Termination." Organometallics 20(3):401-407. 

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