Raymond Addleman

Pacific Northwest National Laboratory
PO Box 999
Richland, WA 99352
(509) 375-6824
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Biography

A significant portion of our present work focuses primarily upon the development of various surface functionalized nanostructured materials for application to sensing and separation challenges in the environmental and security sectors. Analytes of interest depend upon the application and include selective capture of toxic heavy metals, toxic organic compounds, radionuclides, and explosives. We are also exploring the use of supercritical and near critical fluids as a "green" approach for the synthesis, purification and surface modification of nanomaterials and complex hierarchically ordered structures.

Research Interests

My interest focus upon application driven development of advanced materials for sensing, separations energy and catalysis

PNNL Patents

U.S. Patent No. 11,581,176, February 14, 2023, "COLLECTION, RELEASE, AND DETECTION OF ANALYTES WITH POLYMER COMPOSITE SAMPLING MATERIALS ".
U.S. Patent No. 11,525,153, December 13, 2022, " METHODS AND SYSTEMS OF CHARACTERIZING AND COUNTING MICROBIOLOGICAL COLONIES ".
U.S. Patent No. 11,168,276, November 9, 2021, "REINFORCED COMPOSITES WITH REPELLENT AND SLIPPERY PROPERTIES".
U.S. Patent No. 10,577,511, March 3, 2020, "STRETCHABLE HYDROPHOBIC MATERIALS AND METHODS FOR MAKING THE SAME ".
U.S. Patent No. 10,533,968, January 14, 2020, "COLLECTION, RELEASE, AND DETECTION OF ANALYTES WITH POLYMER COMPOSITE SAMPLING MATERIALS ".
U.S. Patent No. 10,453,664, October 22, 2019, "COLLECTION, RELEASE, AND DETECTION OF ANALYTES WITH POLYMER COMPOSITE SAMPLING MATERIALS ".
U.S. Patent No. 10,360,667, July 23, 2019, "Biological Material Fouling Assessment Systems and Methods".
U.S. Patent No. 10,315,185, June 11, 2019, "POLYFUNCTIONAL SORBENT MATERIALS".
U.S. Patent No. 10,254,248, April 9, 2019, "COLLECTION, RELEASE, AND DETECTION OF ANALYTES WITH POLYMER COMPOSITE SAMPLING MATERIALS ".
U.S. Patent No. 10,221,321, March 5, 2019, "PAINTABLE HYDROPHOBIC AND LUBRICANT-INFUSED SURFACE COATINGS AND PROCESSES FOR MAKING AND USING SAME".
U.S. Patent No. 10,005,999, June 26, 2018, " METHOD AND APPARATUS FOR MEASURING BIOFILM THICKNESS AND TOPOLOGY ".
U.S. Patent No. 9,370,749, June 21, 2016, "POROUS MULTI-COMPONENT MATERIAL FOR THE CAPTURE AND SEPARATION OF SPECIES OF INTEREST".
U.S. Patent No. 9,259,708, February 12, 2016, "Device and Method for Enhanced Collection and Assay of Chemicals with High Surface Area Ceramic".
U.S. Patent No. 8,943,910, February 3, 2015, "Enhanced Surfaces Sampler and Process for Collection and Release of Analytes".
U.S. Patent No. 8,679,458, March 25, 2014, "Functionalized Magnetic Nanoparticle Analyte Sensor".
U.S. Patent No. 7,955,574, June 7, 2011, "Porous Thin Film and Process for Analyte Preconcentation and Determination".

PNNL Publications

2024

Addleman R.S., L.F. Pease, M.J. Minette, C. Burns, and W. Chouyyok. 2024. Advanced Mineral Extraction and Water Processing: Application Development of Mesofluidic Separation Technology. PNNL-35843. Richland, WA: Pacific Northwest National Laboratory. Advanced Mineral Extraction and Water Processing: Application Development of Mesofluidic Separation Technology
Nims M.K., E.H. Denis, G.L. Hart, N.M. Escobedo Avalos, S.E. Murphy, R.S. Addleman, and I. Novosselov, et al. 2024. "Standoff trace explosives vapor detection at meter distances." Talanta 270. PNNL-SA-189824. doi:10.1016/j.talanta.2023.125562

2022

Bonheyo G.T., and R.S. Addleman. 2022. Scale up, Field testing, and Optimization of Nontoxic, Durable, Economical Coatings for Control of Biofouling and Corrosion - CRADA 527. PNNL-32936. Richland, WA: Pacific Northwest National Laboratory. Scale up, Field testing, and Optimization of Nontoxic, Durable, Economical Coatings for Control of Biofouling and Corrosion - CRADA 527
Larimer C.J., and R.S. Addleman. 2022. Enhancing Lifetime and Reducing Costs for Fish Diversion Netting Structures - CRADA 529 (Abstract). PNNL-32935. Richland, WA: Pacific Northwest National Laboratory. Enhancing Lifetime and Reducing Costs for Fish Diversion Netting Structures - CRADA 529 (Abstract)
Larimer C.J., R.S. Addleman, W. Chouyyok, and S.M. Pennell. 2022. Durable Super-Repellant Materials for Stretchable and Flexible Personal Protective Equipment. PNNL-32739. Richland, WA: Pacific Northwest National Laboratory. Durable Super-Repellant Materials for Stretchable and Flexible Personal Protective Equipment

2021

Addleman R.S., A.J. Schmidt, L.F. Pease, M.J. Minette, M.R. Thorson, W. Chouyyok, and S. Lee, et al. 2021. Hydrothermal Liquid Recovery of Rare Earth Elements and Critical Materials. PNNL-31328. Richland, WA: Pacific Northwest National Laboratory. Hydrothermal Liquid Recovery of Rare Earth Elements and Critical Materials

2019

Larimer C.J., M.R. Brann, J.D. Powell, M.J. Marshall, J.D. Suter, and R.S. Addleman. 2019. "Rapid nondestructive measurement of bacterial cultures with 3D interferometric imaging." Scientific Reports 9. PNNL-SA-137620. doi:10.1038/s41598-019-43839-7
Yantasee W., G.E. Fryxell, K. Pattamakomsan, T. Sangvanich, R.J. Wiacek, B.J. Busche, and R.S. Addleman, et al. 2019. "Selective capture of radionuclides (U, Pu, Th, Am and Co) using functional nanoporous sorbents." Journal of Hazardous Materials 366. PNNL-SA-138147. doi:10.1016/j.jhazmat.2018.12.043

2018

Laudal D.A., S.A. Benson, R.S. Addleman, and D. Palo. 2018. "Leaching Behavior of Rare Earth Elements in Fort Union Lignite Coals of North America." International Journal of Coal Geology 191. PNNL-SA-133066. doi:10.1016/j.coal.2018.03.010

2017

Barrett C.A., W. Chouyyok, R.J. Speakman, K.B. Olsen, and R.S. Addleman. 2017. "Rapid Extraction and Assay of Uranium from Environmental Surface Samples." Talanta 173. PNNL-SA-116891. doi:10.1016/j.talanta.2017.05.052
Brann M.R., J.D. Suter, R.S. Addleman, and C.J. Larimer. 2017. "Monitoring Bacterial Biofilms with a Microfluidic Flow Chip Designed for Imaging with White-Light Interferometry." Biomicrofluidics 11, no. 4:044113. PNNL-SA-126357. doi:10.1063/1.4985773
Larimer C.J., M.R. Brann, J.D. Suter, and R.S. Addleman. 2017. "Design of a dynamic biofilm imaging cell for white-light interferometric microscopy." Optical Engineering 56, no. 11:Article No. 111708. PNNL-SA-123163. doi:10.1117/1.OE.56.11.111708
O'Hara M.J., and R.S. Addleman. 2017. "Magnetic iron oxide nanoparticles for the collection and direct measurement of adsorbed alpha-emitting radionuclides from environmental waters by liquid scintillation analysis." Analytical Methods 9, no. 19:2791-2804. PNNL-SA-123136. doi:10.1039/C7AY00247E

2016

Chouyyok W., C.L. Warner, K.E. Mackie, M.G. Warner, G.A. Gill, and R.S. Addleman. 2016. "Nanostructured Metal Oxide Sorbents for the Collection and Recovery of Uranium from Seawater." Industrial and Engineering Chemistry Research 55, no. 15:4195-4207. PNNL-SA-113189. doi:10.1021/acs.iecr.5b03650
Chouyyok W., J.T. Bays, A.A. Gerasimenko, A.D. Cinson, R.G. Ewing, D.A. Atkinson, and R.S. Addleman. 2016. "Improved Explosive Collection and Detection with Rationally Assembled Surface Sampling Materials." RSC Advances 97. PNNL-SA-116210. doi:10.1039/C6RA20157A
Chouyyok W., J.W. Pittman, M.G. Warner, K.M. Nell, D.C. Clubb, G.A. Gill, and R.S. Addleman. 2016. "Surface Functionalized Nanostructured Ceramic Sorbents for the Effective Collection and Recovery of Uranium from Seawater." Dalton Transactions 45, no. 28:11312-11325. PNNL-SA-114269. doi:10.1039/c6dt01318j
Gill G.A., L. Kuo, C.J. Janke, J. Park, R.T. Jeters, G.T. Bonheyo, and H. Pan, et al. 2016. "The Uranium from Seawater Program at the Pacific Northwest National Laboratory: Overview of Marine Testing, Adsorbent Characterization, Adsorbent Durability, Adsorbent Toxicity, and Deployment Studies." Industrial and Engineering Chemistry Research 55, no. 15:4264-4277. PNNL-SA-113457. doi:10.1021/acs.iecr.5b03649
Larimer C.J., E.M. Winder, R.T. Jeters, M.S. Prowant, I. Nettleship, R.S. Addleman, and G.T. Bonheyo. 2016. "A Method for Rapid Quantitative Assessment of Biofilms with Biomolecular Staining and Image Analysis." Analytical and Bioanalytical Chemistry 408, no. 3:999-1008. PNNL-SA-111904. doi:10.1007/s00216-015-9195-z
Larimer C.J., J.D. Suter, G.T. Bonheyo, and R.S. Addleman. 2016. "IN SITU NON-DESTRUCTIVE MEASUREMENT OF BIOFILM THICKNESS AND TOPOLOGY IN AN INTERFEROMETRIC OPTICAL MICROSCOPE." Journal of Biophotonics 9, no. 6:656-666. PNNL-SA-108142. doi:10.1002/jbio.201500212
Larimer C.J., M.R. Brann, J.D. Suter, G.T. Bonheyo, and R.S. Addleman. 2016. "Are those bugs reflective? Non-destructive biofilm imaging with white light interferometry." In Interferometry XVIII, August 28, 2016, San Diego, California. Proceedings of SPIE, edited by K Creath, J Burk and AA Goncalves, 9960, Paper No. 996004. Bellingham, Washington:SPIE. PNNL-SA-119531. doi:10.1117/12.2239375
McNamara B.K., M.J. O'Hara, A.M. Casella, J.C. Carter, R.S. Addleman, and P.J. MacFarlan. 2016. "Uniform deposition of uranium hexafluoride (UF6): Standardized mass deposits and controlled isotopic ratios using a thermal fluorination method." Talanta 154. PNNL-SA-109983. doi:10.1016/j.talanta.2016.03.054
Nell K.M., S.A. Fontenot, T.G. Carter, M.G. Warner, C.L. Warner, R.S. Addleman, and D.W. Johnson. 2016. "Non-Covalent Functionalization of High-Surface Area Nanomaterials: A New Class of Sorbent Materials." Environmental Science: Nano 3, no. 1:138-145. PNNL-SA-113262. doi:10.1039/C5EN00170F
O'Hara M.J., J.C. Carter, C.L. Warner, M.G. Warner, and R.S. Addleman. 2016. "Magnetic iron oxide and manganese-doped iron oxide nanoparticles for the collection of alpha-emitting radionuclides from aqueous solutions." RSC Advances 6, no. 2016:105239-105251. PNNL-SA-119737. doi:10.1039/C6RA22262E
Park J., G.A. Gill, J.E. Strivens, L. Kuo, R.T. Jeters, A. Avila, and J.R. Wood, et al. 2016. "Effect of biofouling on the performance of amidoxime-based polymeric uranium adsorbents." Industrial and Engineering Chemistry Research 55, no. 15:4328-4338. PNNL-SA-113339. doi:10.1021/acs.iecr.5b03457
Willingham D.G., B.E. Naes, P.G. Heasler, M.M. Zimmer, C.A. Barrett, and R.S. Addleman. 2016. "Image segmentation for uranium isotopic analysis by SIMS: Combined adaptive thresholding and marker controlled watershed approach." Journal of Vacuum Science and Technology Part B. Nanotechnology & Microelectronics 34, no. 3:Article No. 03H106. PNNL-SA-112280. doi:10.1116/1.4940150

2014

Sangvanich T., J. Morry, C. Fox, W. Ngamcherdtrakul, S. Goodyear, D.J. Castro, and G.E. Fryxell, et al. 2014. "Novel Oral Detoxification of Mercury, Cadmium, And Lead with Thiol-Modified Nanoporous Silica." ACS Applied Materials & Interfaces 6, no. 8:5483-5493. PNNL-SA-107229. doi:10.1021/am5007707

2013

Overman N.R., E.W. Hoppe, and R.S. Addleman. 2013. "Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE." Journal of Radioanalytical and Nuclear Chemistry 296, no. 3:1303-1310. PNNL-SA-90977. doi:10.1007/s10967-012-2301-1
Sundaram S.K., C.A. Sacksteder, T.J. Weber, B.J. Riley, R.S. Addleman, B.J. Harrer, and J.W. Peterman. 2013. "Fourier-transform infrared spectroscopy for rapid screening and live-cell monitoring: application to nanotoxicology." Nanomedicine 8, no. 1:145-156. PNNL-SA-92373. doi:10.2217/nnm.12.186

2012

Davidson J.D., R.J. Wiacek, S.D. Burton, X.S. Li, G.E. Fryxell, R.S. Addleman, and W. Yantasee, et al. 2012. "Improved deposition and deprotection of silane tethered 3,4 hydroxypyridinone (HOPO) ligands on functionalized nanoporous silica." Inorganic Chemistry Communications 18. PNNL-SA-79344. doi:10.1016/j.inoche.2012.01.025
Johnson B.E., P.H. Santschi, C. Chuang, S. Otosaka, R.S. Addleman, M. Douglas, and R.D. Rutledge, et al. 2012. "Collection of Lanthanides and Actinides from Natural Waters with Conventional and Nanoporous Sorbents." Environmental Science & Technology 46, no. 20:11251-11258. PNNL-SA-91370. doi:10.1021/es204192r
Warner C.L., W. Chouyyok, K.E. Mackie, D. Neiner, L. Saraf, T.C. Droubay, and M.G. Warner, et al. 2012. "Manganese Doping of Magnetic Iron Oxide Nanoparticles: Tailoring Surface Reactivity for a Regenerable Heavy Metal Sorbent." Langmuir 28, no. 8:3931-3937. PNNL-SA-81002. doi:10.1021/la2042235

2011

Johnson B., P.H. Santschi, R.S. Addleman, M. Douglas, J.D. Davidson, G.E. Fryxell, and J.M. Schwantes. 2011. "Optimization and Evaluation of Mixed-Bed Chemisorbents for Extracting Fission and Activation Products from Marine and Fresh Waters." Analytica Chimica Acta 708, no. 1-2:52-60. PNNL-SA-78968. doi:10.1016/j.aca.2011.08.017
Kim B.C., J. Lee, W. Um, J. Kim, J. Joo, J.H. Lee, and J. Kwak, et al. 2011. "Magnetic mesoporous materials for removal of environmental wastes." Journal of Hazardous Materials 192, no. 3:1140-1147. PNNL-SA-83057. doi:10.1016/j.jhazmat.2011.06.022
O'Hara M.J., J.C. Carter, J.A. Maclellan, C.L. Warner, M.G. Warner, and R.S. Addleman. 2011. "Investigation of magnetic nanoparticles for the rapid extraction and assay of alpha-emitting radionuclides from urine: Demonstration of a novel radiobioassay method." Health Physics 101, no. 2:196-208. PNNL-SA-76192.
Wai C.M., Y. Liao, W. Liao, G. Tian, R.S. Addleman, D. Quach, and S.P. Pasilis, et al. 2011. "Uranium Dioxide in Ionic Liquid with a Tri-n-butylphosphate-HNO3 Complex - Dissolution and Coordination Environment." Dalton Transactions 40, no. 18:5039-5045. PNNL-SA-78548. doi:10.1039/C0DT01518K

2010

Fontenot S.A., T.G. Carter, D.W. Johnson, R.S. Addleman, M.G. Warner, W. Yantasee, and C.L. Warner, et al. 2010. "Nanostructured materials for selective collection of trace-level metals from aqueous systems." In Trace Analysis with Nanomaterials, edited by D.T. Pierce and J.X. Zhao. 191-221. PNNL-SA-65531. doi:10.1002/9783527632015.ch8
Johnson B.E., P.H. Santschi, R.S. Addleman, M. Douglas, J.D. Davidson, G.E. Fryxell, and J.M. Schwantes. 2010. "Collection of fission and activation product elements from fresh and ocean waters: a comparison of traditional and novel sorbents." Applied Radiation and Isotopes 69, no. 1:205-216. PNNL-SA-71107. doi:10.1016/j.apradiso.2010.07.025
Rutledge R.D., C.L. Warner, J.W. Pittman, R.S. Addleman, M.H. Engelhard, W. Chouyyok, and M.G. Warner. 2010. "Thiol-Ene Induced Diphosphonic Acid Functionalization of Superparamagnetic Iron Oxide Nanoparticles." Langmuir 26, no. 14:12285-12292. PNNL-SA-71652.
Sangvanich T., V. Sukwarotwat, R.J. Wiacek, R.M. Grudzien, G.E. Fryxell, R.S. Addleman, and C. Timchalk, et al. 2010. "Selective Capture of Cesium and Thallium from Natural Waters and Simulated Wastes with Copper Ferrocyanide Functionalized Mesoporous Silica." Journal of Hazardous Materials 182, no. 1-3:225-231. PNNL-SA-66353. doi:10.1016/j.jhazmat.2010.06.019
Timchalk C., J.A. Creim, V. Sukwarotwat, R.J. Wiacek, R.S. Addleman, G.E. Fryxell, and W. Yantasee. 2010. "In Vitro and In Vivo Evaluation of a Novel Ferrocyanide Functionalized Nanopourous Silica Decorporation Agent for Cesium in Rats." Health Physics 99, no. 3:420-429. PNNL-SA-66555. doi:10.1097/HP.0b013e3181bca9b0
Yantasee W., R.D. Rutledge, W. Chouyyok, V. Sukwarotwat, G. Orr, C.L. Warner, and M.G. Warner, et al. 2010. "Functionalized Nanoporous Silica for Removal of Heavy Metals from Biological Systems; Adsorption and Application." ACS Applied Materials & Interfaces 2, no. 10:2749-2758. PNNL-SA-73483. doi:10.1021/am100616b
Yantasee W., T. Sangvanich, J.A. Creim, K. Pattamakomsan, R.J. Wiacek, G.E. Fryxell, and R.S. Addleman, et al. 2010. "Functional Sorbents for Selective Capture of Plutonium, Americium, Uranium, and Thorium in Blood." Health Physics 99, no. 3:413-419. PNNL-SA-67059.

2009

Busche B.J., R.J. Wiacek, J.D. Davidson, V. Koonsiripaiboon, W. Yantasee, R.S. Addleman, and G.E. Fryxell. 2009. "Synthesis of Nanoporous Iminodiacetic Acid Sorbents for Binding Transition Metals." Inorganic Chemistry Communications 12, no. 4:312-315. PNNL-SA-63114.
Fernandez C.A., J. Roberts, E.M. Hoppes, G.E. Fryxell, C.M. Wang, J.T. Bays, and M.G. Warner, et al. 2009. "Effect of the Ligand Shell Composition on the Dispersibility and Transport of Gold Nanocrystals in Near Critical Solvents." Langmuir 25, no. 9:4900-4906. PNWD-SA-8342. doi:10.1021/la804058x
Fernandez C.A., J. Roberts, E.M. Hoppes, R.J. Wiacek, G.E. Fryxell, J.T. Bays, and M.G. Warner, et al. 2009. "Advancements Toward the Greener Processing of Engineered Nanomaterials -- Effect of Core Size on the Dispersibility and Transport of Gold Nanocrystals in Near-Critical Solvents." Small 5, no. 8:961-969. PNWD-SA-8223. doi:10.1002/smll.200801207
Schwantes J.M., R.S. Addleman, J.D. Davidson, M. Douglas, D.E. Meier, O. Mullen, and M.J. Myjak, et al. 2009. "Medium-resolution Autonomous in situ Gamma Detection System for Marine and Coastal Waters." Journal of Radioanalytical and Nuclear Chemistry 282, no. 3:889-895. PNNL-SA-65989. doi:10.1007/s10967-009-0325-y
Wang J.S., J.S. Wang, C.N. Sheaff, B. Yoon, R.S. Addleman, and C.M. Wai. 2009. "Extraction of Uranium from Aqueous Solutions Using Ionic Liquid and Supercritical Carbon Dioxide in Conjunction." Chemistry - A European Journal 15, no. 17:4458-4463. PNNL-SA-60724.
Warner M.G., C.L. Warner, R.S. Addleman, and W. Yantasee. 2009. "Magnetic Nanomaterials for Environmental Sensing." In Nanomaterials for the Life Sciences: Magnetic Nanomaterials, edited by CSSR Kumar. 311-344. Weinheim:Wiley-VCH Verlag GmbH & Co. KGaA. PNNL-SA-63088.
Warner M.G., C.L. Warner, R.S. Addleman, T.C. Droubay, M.H. Engelhard, J.D. Davidson, and A.D. Cinson, et al. 2009. "Synthesis of Functionalized Superparamagnetic Iron Oxide Nanoparticles from a Common Precursor and their Application as Heavy Metal and Actinide Sorbents." In Abstracts of Papers of the 237th ACS National Meeting, March 22-26, 2009, Salt Lake City, Utah, COLL-465. Washington Dc:American Chemical Society. PNNL-SA-65452.
Yantasee W., G.E. Fryxell, R.S. Addleman, R.J. Wiacek, V. Koonsiripaiboon, K. Pattamakomsan, and V. Sukwarotwat, et al. 2009. "Selective Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate." Journal of Hazardous Materials 168, no. 2-3:1233-1238. PNNL-SA-61637.

2008

Carter T.G., W. Yantasee, T. Sangvanich, G.E. Fryxell, D.W. Johnson, and R.S. Addleman. 2008. "New functional materials for heavy metal sorption: “Supramolecular” attachment of thiols to mesoporous silica substrates." Chemical Communications 43. PNNL-SA-60911. doi:10.1039/b810576f
Fernandez C.A., E.M. Hoppes, J.G. Bekhazi, C.M. Wang, R.J. Wiacek, M.G. Warner, and G.E. Fryxell, et al. 2008. "Tuning and Quantifying the Dispersibility of Gold Nanocrystals in Liquid and Supercritical Solvents." Journal of Physical Chemistry C 112, no. 36:13947-13957. PNWD-SA-8129. doi:10.1021/jp8038237
Fernandez C.A., R.J. Wiacek, P. Nachimuthu, G.E. Fryxell, A.M. Pierson, C.L. Warner, and M.G. Warner, et al. 2008. "A Simple Method for the Prevention of Non-Specific Adsorption by Nanocrystals onto Surfaces." Journal of Nanoscience and Nanotechnology 8, no. 11:5781-5786. PNWD-SA-7926. doi:10.1166/jnn.2008.320
Sheaff C.N., D. Eastwood, C.M. Wai, and R.S. Addleman. 2008. "Fluorescence Detection and Identification of Tagging Agents and Impurities Found in Explosives." Applied Spectroscopy 62, no. 7:739-746. PNNL-SA-62928. doi:10.1366/000370208784909652
Yantasee W., B. Charnhattakorn, G.E. Fryxell, Y. Lin, C. Timchalk, and R.S. Addleman. 2008. "Detection of Cd, Pb, and Cu in non-pretreated natural waters and urine with thiol functionalized mesoporous silica and Nafion composite electrodes." Analytica Chimica Acta. PNNL-SA-59334. doi:10.1016/j.aca.2008.05.029
Yantasee W., K. Hongsirikarn, C.L. Warner, D. Choi, T. Sangvanich, M.B. Toloczko, and M.G. Warner, et al. 2008. "Direct detection of Pb in urine and Cd, Pb, Cu, and Ag in natural waters using electrochemical sensors immobilized with DMSA functionalized magnetic nanoparticles." The Analyst 133, no. 3:348-355. PNNL-SA-57442. doi:10.1039/b711199a

2007

Dutta D., S.K. Sundaram, J.G. Teeguarden, B.J. Riley, L.S. Fifield, J.M. Jacobs, and R.S. Addleman, et al. 2007. "Adsorbed Proteins Influence the Biological Activity and Molecular Targeting of Nanomaterials." Toxicological Sciences 100, no. 1:303-315. PNNL-SA-55139. doi:10.1093/toxsci/kfm217
Fryxell G.E., S.V. Mattigod, Y. Lin, H. Wu, S.K. Fiskum, K.E. Parker, and F. Zheng, et al. 2007. "Design and Synthesis of Self-Assembled Monolayers on Mesoporous Supports (SAMMS): The Importance of Ligand Posture in Functional Nanomaterials." Journal of Materials Chemistry 17. PNNL-SA-54650. doi:10.1039/b702422c
Yantasee W., C.L. Warner, T. Sangvanich, R.S. Addleman, T.G. Carter, R.J. Wiacek, and G.E. Fryxell, et al. 2007. "Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized Superparamagnetic Nanoparticles." Environmental Science & Technology 41, no. 14:p.5114-5119. PNNL-SA-53961. doi:10.1021/es0705238
Yantasee W., Y. Lin, K. Hongsirikarn, G.E. Fryxell, R.S. Addleman, and C. Timchalk. 2007. "Electrochemical Sensors for the Detection of Lead and Other Toxic Heavy Metals: The Next Generation of Personal Exposure Biomonitors." Environmental Health Perspectives 115, no. 12:1683-1690. PNWD-SA-7728.
Zheng F., R.S. Addleman, C.L. Aardahl, G.E. Fryxell, D.R. Brown, and T.S. Zemanian. 2007. "Amine Functionalized Nanoporous Materials for Carbon Dioxide Capture." In Environmental Applications of Nanomaterials: Synthesis, Sorbents and Sensors, edited by Glen E. Fryxell and Guozhong Cao. 285-312. London:Imperial College Press. PNNL-SA-50728.

2005

Addleman R.S., M.J. O'Hara, J.W. Grate, and O.B. Egorov. 2005. "Chemically Enhanced Alpha-Energy Spectroscopy in Liquids." Journal of Radioanalytical and Nuclear Chemistry 263, no. 2:291-294. PNNL-SA-40022.
Addleman R.S., M.J. O'Hara, T.D. Marks, J.W. Grate, and O.B. Egorov. 2005. "Direct Actinide Assay with Surface Passivated Silicon Diodes." Journal of Radioanalytical and Nuclear Chemistry 263, no. 2:295-300. PNNL-SA-39879.
Addleman R.S., O.B. Egorov, M.J. O'Hara, B.J. Busche, T.S. Zemanian, and G.E. Fryxell. 2005. "Preconcentration and Assay of Radionuclides with Self Assembled Monolayers on Mesoporous Supports." Journal of Radioanalytical and Nuclear Chemistry 263, no. 1:59-64. PNNL-SA-43186.
Egorov O.B., R.S. Addleman, M.J. O'Hara, T.D. Marks, and J.W. Grate. 2005. "Direct Measurement of Alpha Emitters in Liquids using Passivated Ion Implanted Planar Silicon (PIPS) Diode Detectors." Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment 537, no. 3:600-609. PNNL-SA-41059.
Williford R.E., R.S. Addleman, X.S. Li, T.S. Zemanian, J.C. Birnbaum, and G.E. Fryxell. 2005. "Pore Shape Evolution in Mesoporous Silica Thin Films: from Circular to Elliptical to Rectangular." Journal of Non-crystalline Solids 351, no. 27-29:2217-2223. PNNL-SA-41313.
Williford R.E., X.S. Li, R.S. Addleman, G.E. Fryxell, S. Baskaran, J.C. Birnbaum, and C.A. Coyle, et al. 2005. "Mechanical Stability of Templated Mesoporous Silica Thin Films." Microporous and Mesoporous Materials 85, no. 3:260-266. PNNL-SA-44235.
Zheng F., D.N. Tran, B.J. Busche, G.E. Fryxell, R.S. Addleman, T.S. Zemanian, and C.L. Aardahl. 2005. "Ethylenediamine-modified SBA-15 as Regenerable CO2 Sorbent." Industrial and Engineering Chemistry Research 44, no. 9:3099-3105. PNNL-SA-41861. doi:10.1021/ie049488t

2004

Bitterwolf T.E., J.D. Newell, C.T. Carver, R.S. Addleman, J.C. Linehan, and G.E. Fryxell. 2004. "Rhodium catalysts bound to functionalized mesoporous silica." Inorganica Chimica Acta 357, no. 10:3001-3006. PNNL-SA-43062.
Fifield L.S., L.R. Dalton, R.S. Addleman, R.A. Galhotra, M.H. Engelhard, G.E. Fryxell, and C.L. Aardahl. 2004. "Noncovalent Functionalization of Carbon Nanotubes with Molecular Anchors using Supercritical Fluids." Journal of Physical Chemistry B 108, no. 25:8737-8741. PNNL-SA-40325.
Fryxell G.E., R.S. Addleman, S.V. Mattigod, Y. Lin, T.S. Zemanian, H. Wu, and J.C. Birnbaum, et al. 2004. "Environmental and Sensing Applications of Molecular Self-Assembly." In Dekker Encyclopedia of Nanoscience and Nanotechnology, edited by J. A. Schwarz, C. Contescu, K. Putyera. 1135-1145. New York:Marcel Dekker. PNNL-SA-38029.

2003

Egorov O.B., M.J. O'Hara, R.S. Addleman, and J.W. Grate. 2003. "Automation of Radiochemical Analysis: From Groundwater Monitoring to Nuclear Waste Analysis." In ACS Symposium Series: Radioanalytical Methods in Interdisciplinary Research., edited by Carola A. Laue and Kenneth L. Nash, 868, 246-270. Washington D.C.:American Chemical Society. PNNL-SA-38624.

2001

Bitterwolf T.E., D.L. Klein, J.C. Linehan, C.R. Yonker, and R.S. Addleman. 2001. "Photochemical Carbonylation of Ethane Under Supercritical Conditions." Angewandte Chemie International Edition 40, no. 14:2692-2694. PNNL-SA-35969.
Linehan J.C., C.R. Yonker, R.S. Addleman, T. Autrey, J.T. Bays, T.E. Bitterwolf, and J.L. Daschbach. 2001. "Solvent Study of the Kinetics of Molybdenum Radical Self-Termination." Organometallics 20, no. 3:401-407. PNNL-SA-34196.